Researchers from the University of Southampton (UK) have demonstrated a new patterning technology that can create high-quality nanostructured optical metasurfaces for infrared thermal control coatings and nonlinear optics.1
Conventional methods of producing optical metasurfaces take place in specialist cleanroom facilities such as the Southampton Nanofabrication Centre, where patterns are etched into materials or separated structures are deposited on the surface by a process called lift-off lithography. However, the resulting surface topography is often undesirable and can strongly limit the device performance when embedded into a stack of many independent layers.
In their study, the Southampton researchers explored a new technology that locally and selectively modulates optical properties without changing the flatness of the material surface. The research team based their new technique on the discovery that an oxygen plasma can greatly reduce the electron concentration of certain metal oxides.
The plasma patterning technique has been demonstrated by fabricating two novel devices: a planar metasurface-based optical solar reflector for satellite radiant cooling, and a multiband metasurface with different operation ranges.
“Plasma patterning provides a completely new route to form electrical and optical devices with structures beyond existing manufacturing limitations,” says Kai Sun, the lead author. “Here, we have shown for the first time that a planar metasurface, based on aluminum-doped zinc oxide, can be achieved with an optical metasurface function but physically flat. The metasurface devices in this work are only a start of this new technique’s applications and its full potential impact is still to be seen.”
Transparent conductive oxides such as aluminum-doped zinc oxide (Al:ZnO) have a high electron density, making it dielectric in visible range but metallic in infrared (IR) range. This electron density of Al:ZnO is critical for its material electrical and optical properties. To achieve an optical property contrast, which is required for optical metasurface formations, parts of the Al:ZnO film need to be removed, leaving a nonplanar structure.
The study found that oxygen plasma can reduce Al:ZnO electron density by up to five orders of magnitude. This led the team to propose the new fabrication technique that forms a metasurface by selectively modulating the electron density using oxygen plasma, made possible by accurate location control through a lithography definition.
The fabricated device achieves its metasurface function via its optical property contrast but maintains a planar topological surface profile. This metasurface is highly desirable for its compatibility with any added functional layers.
Southampton scientists have applied to file the plasma patterning technique as a UK patent.
Source: https://www.ecs.soton.ac.uk/news/6755
REFERENCE:
Kai Sun et al., Advanced Materials (2020); https://doi.org/10.1002/adma.202001534
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John Wallace | Senior Technical Editor (1998-2022)
John Wallace was with Laser Focus World for nearly 25 years, retiring in late June 2022. He obtained a bachelor's degree in mechanical engineering and physics at Rutgers University and a master's in optical engineering at the University of Rochester. Before becoming an editor, John worked as an engineer at RCA, Exxon, Eastman Kodak, and GCA Corporation.